前苏联专利SU727105A3 Fungicidic agent

专利PDF首页>>前苏联专利

专利附录

专利说明

权利要求

类似技术

同族专利

引用文献

法律状态

优先权

专利摘要:
Azolyl ether derivatives of the formula <IMAGE> in which A is CH or a nitrogen atom, R is alkyl, alkenyl, alkynyl, phenyl, benzyl or substituted phenyl or benzyl, X is halogen, alkyl, alkoxy, alkylthio, alkylsulphonyl, halogenoalkyl, alkoxycarbonyl, nitro, cyano, phenyl, phenoxy, phenylthio, or substituted phenyl, phenoxy of phenylthio, Y is alkyl, phenyl, or substituted alkyl or phenyl and n is 0, 1, 2, 3, 4 or 5, which possess fungicidal properties.
公开号:SU727105A3
申请号:SU782612099
申请日:1978-05-06
公开日:1980-04-05
发明作者:Крэмер Вольфганг；Гейнц Бюхель Карл；Брандес Вильгельм；Фробергер Пауль-Эрнст；Пауль Фолькер
申请人:Байер Аг (Фирма)；
IPC主号:

专利说明:

372 zapachest and G1a means chlorine or bromine, in the presence of 5I1 {solvent. Derivatives of the azolyl formula (1) thus considered by the interaction with acids can be converted to comi. Inert organic solvents such as ethers, benzene, chlorinated hydrocarbons, and hexamethylphosphoric triamide are suitable as solvents for the reagents. The temperature of the reaction can be varied in the ujHpOKOH region. Usually, the reaction is carried out at temperatures TijH of 20-150 ° C, preferably at a temperature of: ():) solvent. In the implementation of the process used, one mole of alkoholta of formula (2) is 1–2 mol of halide of formula (3). To isolate the non-product, the reaction mixture is freed from the solvent and a hearth and an organic solvent are added to the residue. The orgagic phase (the phase is separated by the usual method of treatment and purified, salt is obtained in the case of lekhodnosti. The proposed actions at the beginning of the region give strong fungithoxic and bacterotoxic actions} Schm1. Osh1 in the concentrations necessary for fungi and bacteria are not harmful to the cultivated plants , therefore, can be used as a means of protecting plants from fungi and bacteria. The compounds of the formula have a umpOKnis spectrum and can be used against infesting fungi that affect the aboveground; parts that are spread, as well as against pathogens that are transmitted by the pathogens. When eum proposed funpdadnom tool treated note, seed and, above-ground part of the plant. d. We offer 1e active principles are made in the form of solutions, emulsions, powders, pastes and granules, naniller, by displacing the active ingredients, ally with diluents, i.e. liquid solvent, under pressure, with With the same gases and / or solids, if necessary, use of surface active agents, i.e. emulsifiers and / or disintegrants and / or pores. In the use of water as an auxiliary solvent diluent, organic solution can also be used. Suitable liquid solvents are aromatic or aliphatic hydrocarbons, chlorinated aromatic or chlorinated aliphatic hydrocarbons, alcohols, as well as their ethers and esters, ketones, forces: polar solvents such as dimethylformamide and dimethyl sulfoxide, as well as water and oxygen. solvents or carriers should be worn such liquids that are gaseous at normal temperature and under normal pressure, for example, aerosol-working gases, such as dichlorodifluoromethane or trichloroformethane; under solid carriers, natural stone L5s, such as kaolin, alumina, talc, chalk, quartz, attagtulgite, montmorillonite or diatomaceous earth, and synthetic stone stones, such as highly dispersed silicic acid, aluminum oxide and silicates; iodine emulsifiers, non-ionic and 1-shonny emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, alkyl sulfonates, alkyl sulfates, ap-sulfonate, as well as protein hydrolysates; under lignin dispersants, spent sulphite liquors and methylcellulose. The proposed active principles in preparations can be mixed with other known active Principles, such as fungicides, insekistits, acaricides, hematicides, herbicides. Sandgents against plant damage with ps1 wounds, plant growth regulators, microelements and ul h: means of soil structure. For example, a solution containing a compound of formula (1) is sprayed to form young droplets of a blond, forming a drop in the developmental stage from 4 to 6 leaves. Spread is left for 24 hours at a temperature of 20 ° C and a relative humidity of 70% in a greenhouse. Then they are inoculated with the KOSH1DIYAMI of the exclu- sive agent dew and then the seedlings are disturbed in a greenhouse with a temperature of 21 to 23 ° C and a relative humidity of approximately 70%. After 10 days after the inoculation, the steppe of the injured sections is defined in%, the Acting principles, their concentrations and the results of the test in Table. 1. Example 2. The young saplings of Blon, which are in stages from 4 to 6 leaves, are sprayed with a solution containing the active principle. The plants are left for 24 hours at a temperature of 20 ° C and a relative air strength of 70% in a greenhouse. Then they are cleaned with an aqueous suspension of conidia of the blonds scab pathogen and incubated in a humid chamber for 18 hours at a temperature of 18 to 20 ° C and a relative humidity of 100%. Thereafter, the plants are re-kept for 14 days in the tagogac. After 15 days after inoculation, damage to the seedlings is determined as in Example 1. The active principles, their concentrations and results are shown in Table. 2. 57 Example 3. The test with the treatment of shoots (mealy dew of cereals) (protective action) ({destroying the leaves of mycosis). For the purpose of determining the protective effect, young plants of barley, have 1 sheet, are sprayed with dew containing moisture to the dew moisture. After drying, vanilla dusted the barley plants with spores of Erysiphe graminis var. hordei. After 6 days of stay of the plants at a temperature of 21 to 22 ° C and a humidity of 80 to 90%, the damage to plants by powdery mildew debris is determined. The degree of damage is expressed in percent of the untreated control plants. In this case, O means no damage, 10 is the same degree of damage as in untreated plants. The active principle is the more effective the smaller the defeat of powdery mildew, the active principle, its concentration in the spray solution and the degree of damage are indicated in table. 3. Example 4. To treat the inoculum in a closed bite, shake the seeds of barley with a powder-containing mixture containing the active principle. Seeds (3x12 seeds) to a depth of 2 cm are sown in flower pots filled with a mixture of ground varieties of frustorfer and quartz sand (1: 1 ob.ch.). Germination and germination take place in favorable conditions in the greenhouse. After 7 days after sowing, the barley plants that develop the first leaf are dusted with fresh spores of the fungus Erysi he graminis var hordei and cultivated under conditions of 21-22 ° C, 80-90% relative humidity and 16-hour exposure. Within 6 days, typical powdery mildew pustules form on the leaves. The degree of damage is determined in the same way as in Example 3. The active principles, their concentration in the seed treatment and the amount taken, as well as the defeat by powdery mildew in% are given in Table. 4. Example 5. A solution containing the active substance is sprayed to form a drop of 30 rice plants of ages 2-4 weeks. Prior to drying, pacieiiHH is left in the greenhouse at a temperature of 22-24 ° C and relative air humidity of .70%. The plants are then inoculated with PEIIicularia sasakii grown on malt agar and kept at a temperature of 28-30 ° C and a relative humidity of 100%. After 5-8 days, leaf damage is determined by comparing with untreated but infected plants. The active principles, their concentrations and results of treatment are shown in Table. 5. Example 6. Effect on mycelium growth. The amount of active ingredient required for the desired concentration of the active principle in the nutrient medium is mixed with the solvent. Concentrate in the required quantitative ratio is thoroughly mixed with liquid medium cooled to 42 ° C and poured into Petri dishes with a diameter of 9 cm. In addition, control plates are provided without admixture of the preparation. After cooling and solidification of the nutrient medium, the plates are incubated with the fungal species indicated in the table and are incubated at a temperature of approximately 2lC. According to the fungal growth rate, the assessment is carried out in 4-10 days. In assessing the radial growth of the mycelium on the treated nutrient media is compared with the growth on the control nutrient media. The assessment of the growth of fungi is assessed as follows: 1 - no growth of fungi; up to 3 - growth retardation is very strong; up to 5 - delayed growth of the average degree; to 7 - weak growth retardation; 9 - growth is equal to the growth of untreated (1) (control) plants. Active principle, their concentration and results are shown in Table. 6. Thus, the proposed compounds have a high fush-search activity at low concentrations.
HE
OjN-C 1-0-CH-4h-C (CH3).
Have
NI
(known)
OH I
SNa) eS- -0-p-CH-C (CH3) d
g
N-1) (known)
C1 P-0-CH-CO-C (CH3) s
x: ifI
xN
Qi
(known) -0-CH-CO S (CH3) d
I
(known)
100
100
O-CHD -0 CH-CH-C (CH3) s

yy
Lj
X HC1
С1гГ
iLj
29
9
- 9-СНа-О
-C1
-0-CH-6n-С (СН,),
N
FROM
X 1/2
OK
r-ns, o-nsn-ns-ssn,) s
Lg
NLI
727105
ten
T 1 table 1
- I 3 80ZN
O-Sig-CH, -0-CH-CH-C (CH3) s
Ly
-Cl o-CHj-CHj
Cl- -0-CH-CH-0 (CHj) j
(f N.J)
Cl p-CH, -CHeCHa 0-fH-CH-C (CH5) h
Cl .xN.N Lll
O-CHj -CH, -0-CH-CH-C (CH3),
AN
about ci
-O-CH-SNSSN3),, H
and JX 1/2
(14)
O-CHg CH3 -0-9H-CH-C (CH3) 5
i
O-CHg-CH CHg 0-CH-CH.-C (CH3) s
-Ljj
CALL
n, - (G D-ci
f
0 -0-CH-CH-С (СНз) з
X HCl
55
Cl
-Cl
CH, I
0 -Cl
O-CH-CH-Cl
l, l
fT N Ji-J
13
CH,
I
ABOUT
I
-C1
o-ch-ch1 I
C1
, |
X HC1
C1, CHA-A C1-0-CH-.CH-C (CH3) s
X HC1 V
0-CHD-0-CH-CH-C (CH5) j
/ c
n 1
11N
O-SNG SND
-o - (: nn sn-c (sn5) 5
about
O-CHaCH, 0-CH-CH-C (CH3) s
VgQ
Note: O - no lesion;
100 - complete destruction of all plants.
14
727105 Number of tables I
50
thirty
57
57
15
he
-0-CH-CH С (СНз) з
S
WITH ,
(known)
C1X HC1
0-CH3-0-CH-CH-C (CH3) j
O-SNG -CHj 0-CH-Sy-C (CH3) s
rN p
11-n
O-CHA-CH ,, Br-G1 -0-CH-CH-C (CH3) s
.Nx.
(1N
727105
16 Table 2
83
54
40
51
40
17
0-CH2-CH CH2
-o- (j: H-iHG (cH,) g
C1
but
n, O-C1
ABOUT
-n-thn-thr
N,
Q
X 1/2
Note: Evaluation is the same as in table. one.
Active shchalo
not processed
Cl OH —0 — CH — C4 — C (CHj),
/ N.
fl i
N-ti
(known)

lQ -0-CH-CH-C (CHj) j
yy
(known)
727105
18 Continued table. 2
67
65
thirty
Table 3
Damage of young barley plants, not treated with the proposed remedy,%, by spores of Erysiphe graminis var. horde i
100
0.01
26.3
0.01
21.3
Cl-C;) - 0-CH-CH-C (CH3) s
L
IN
0-CHj -CHj (Y-CH-CH-CCCH) h
,to.
Q
0-SNg-CH CH
-o-CH-iH-cCcHy),
fi a
0-CH2-CY CH2 -0-CH-4n-C (CH3) s
.S
And uN
C1
;on
About C.L-0-CH-CH-C (CH5) s
N,

R
N0 .0
0,0025
0.0
0,0025
0,0025
36.3
0.0025
0.0
0,0025
12.5
j: Ha - (()) - C1

.0-CH-CH-С (СНз) з N.N N-ОX 1/2
0,0025
0.0
727105
23
24 Continuation of table 3
ABOUT
I
C1 - (()) - 0-CH-CH-C (CH3) s
N
N-i
X 1/2
0,0025
0.0

sn.
Q -0 CH-CH-C (CH3) g
N
R f-j
0,0025
0.0
СНз 0-СН-СН-С (СНз) з
.N if-J
Cl
On
R
CI 0-CH "CH-C (CH3) s
) X HCl
0.0
0,0025
0,0025
0.0
Cl О-СНг-СНз -О-СН-СНСССНз) з
f 1-l
Cl О-СНг-CH CHj -0-СН-СН-СССНз) з
k
but
0,0025
0.0
0.0
0,0025
-SCg -CHj C1-)) - 0-CH-CH-C (CH3) s
yy
N-il
C1
SNGS1 about C1
0-0-CH-CH-С (СНз) з
1N.
X 1/2
ff
N
N (j) -CHa-CH, C1-O- (C1-0-CH-CH-C (CH3) C
Lg
Nlj
Continued table. 3
0,0025
0.0
0,0025
0.0
50zN
0,0025
0.0
O-CHa-CH CH
-0-CH-CH "C (CH3) s
g
N
0.0
0,0025
O-CHA-CH-CHa 1) -0-CH-CH-C (CH3) s

AND
Note: O10 -0, 0025
0.0 no lesion; the same degree of damage as untreated plants.
Table 4
OH-0-CH-CH-C (CH3) s
V
25
ten
100
(known)
OH I
-s-ns -sn (SNZ) zS
Jh
about
(known)
C1
OH I
-n -sn -sn-sd (dNz) s
ff.-N 11 II N - IJ
(known)
O-0-CH-CH-C (CH3) 5
II |
N. 1 X HC1
C1
si
I
about
-0-CH-CH-С (СНз) з
1 x 1/2 p
ZZ, N
ten
25
100
100
ten
25
10.0
ten
25
25
0.0
ten
29
SN
-Cl O GZ-0-CH-CH-C (CH5) g
/ Nvn conscious
And X1 / 2QO
9-si
-0-CH-CH-C (CHj) h
I, N,
About II
N

SNG-O
C1 / -0-CH-CH-C (CH3),
I |
NI
C1
h
CH2-
-0-CH-CH-С (СН5) з
/ h
it-jl
Note: The assessment is the same as in table. 3
727105
30 Continuation of table 4
0.0
ten
25
0.0
ten
25
55.0
ten
25
33
ten
25
31727105
Pell icularia - test
Active principle
-0-CH-CH-С (СНз) з
VG X nx
N (lime (
oh,
one
C1- (L-0-CH-CH-C (CH5) h.
N
O-CHg CH3 -0-CH-CH-C (CH3) s
I, N,
G4
O-SNG CH3 -O-CH-CH-SCHNz) s
Vg
s
1 - 100% effect;
tagging 3 is a good action;
5 - minor effect; 9 - no action.
32
Table 5
The degree of damage to rice by pathogens Pell icularia sasakii,%, with a concentration of 1 active ingredient 0.025%
-n-ns-ns-n (n, n)
G1
N
.x
P 1 11N
(known)
X hjo x hc1
(known)
(jl-CH, -0-CH-CH-C (CH3) s
C1U
0-CH, CH, I
C1 - (()) - 0-CH-CH-C (CH3),
N
O-CHj CH3) -0-CH-CH-C (CH3) 5
f "
9 3
53111
55131
3131
O-CHj 0-CH-CH-C (CH3) C N.
(
AND
c-.N
-CH-CH.
-11-U
O-o-ns-n-ns (n, n) h
N.
)one

权利要求:
Claims (2)
[1]
- N Claims of the invention A fungicidal agent containing an active principle based on the production of azolyl ether, as well as an additive selected from the groups of solid and liquid carriers, characterized in that, in order to increase its ficidic activity, it contains the compounds General formula -O- {H-CH-Y LA “in which A — CH is a nitrogen group or atom, R is methyl, ethyl, propyl, 4-chlorobenzyl, 2,4- or 2,6-dichlorobenzyl, X - 4-chloro, 2,4-dichloro, 4-bromo, 4-phenyl or 4-chloroethiyl. U-tertiary butyl or 2,4-d-lorphenyl are p-integers I or 2, or their salts with hydrochloric or 1,5-naphthalene disulfonic acid, and the content of the active principle in the agent is 0.195 wt%. Sources of information taken into account in the examination 1. US patent number 397289, cl. 260-308, published. 08/08/76.
[2]
2. Patent of Germany No. 2325156, cl. 45 6 9/22, off., 05.12.74 (prototype).

类似技术:

公开号 | 公开日 | 专利标题

SU727105A3|1980-04-05|Fungicidic agent

JP4416851B2|2010-02-17|Bactericidal and fungicidal 2-methoxybenzophenones

HU215118B|1998-09-28|Amino-acid amide derivatives, process for preparing the same, agricultural or horticultural fungicides, and method for killing fungi

DK160937B|1991-05-06|1,2,4-TRIAZOLYL COMPOUNDS, PROCEDURES FOR THE PREPARATION OF SUCH COMPOUNDS, AND PLANT PROTECTIVE CONTAINING THESE COMPOUNDS

DK154651B|1988-12-05|Substituted N- | -N-aminoacetyl-anilines and their salts with inorganic and organic acids for controlling phytopathogenic fungi, fungicide and method for controlling phytopathogenic fungi or for preventing OF FUNGI ATTACKS

SU511832A3|1976-04-25|Fungicide and microbicide

JP3775841B2|2006-05-17|Agricultural / horticultural fungicide composition

DE2350944A1|1974-04-25|N- | -N-HALOACETYL-2,6-DIALKYLANILINE FOR THE CONTROL OF PHYTOPATHOGENIC FUNGI AND BACTERIA

RU2129788C1|1999-05-10|Method of suppression of phytopathogen fungi, derivative of benzophenone, a method of protection of plants from damage caused by phytopathogen fungus, a fungicide composition, methods of synthesis of benzophenones

SU515428A3|1976-05-25|The way to combat fungal plant diseases

DK141440B|1980-03-17|Fungicide N-acyl anilinoacetic acid esters for use in plant protection.

PL101196B1|1978-12-30|FUNGICIDE

IE47663B1|1984-05-16|Phenyl isothiocyanate derivatives

PL100897B1|1978-11-30|FUNGICIDE

US4287210A|1981-09-01|Microbicidal meta oxy- and thio-substituted phenylanilines

CZ466989A3|1998-02-18|Oximether derivative, fungicidal agent containing thereof and method of fighting fungi

CA1206969A|1986-07-02|2-aryl-2-1-h-azoyl|-gamma-butyrolactones

SU1452454A3|1989-01-15|Method of controlling undesirable vegetation

CH623458A5|1981-06-15|

SU1450737A3|1989-01-07|Method of producing derivatives of 9.10-phenanthredione

KR900006709B1|1990-09-17|Process for the preparation of sulf enylated acylhydrazones

PL69661B1|1973-08-31|

US4372972A|1983-02-08|N-Substituted alkynyl anilines

US4590198A|1986-05-20|Fungicidal isonicotinanllide retals, their compositions and method of using them

US4596801A|1986-06-24|4H-3,1-benzoxazine derivatives, process for producing the same and agricultural or horticultural fungicide containing the same

同族专利:

公开号 | 公开日

JPS623147B2|1987-01-23|

CS194844B2|1979-12-31|

BR7802913A|1979-01-02|

IE780935L|1978-11-10|

DE2720949A1|1978-11-23|

GB1583311A|1981-01-21|

DD137049A5|1979-08-15|

TR19749A|1979-11-27|

IE46885B1|1983-10-19|

US4229459A|1980-10-21|

IT7823137D0|1978-05-08|

PL206645A1|1979-02-12|

ES469615A1|1978-12-16|

JPS53141273A|1978-12-08|

SE7805269L|1978-11-11|

OA05960A|1981-06-30|

IL54664A|1983-03-31|

AU517864B2|1981-09-03|

BG28694A3|1980-06-16|

AT363721B|1981-08-25|

NZ187196A|1979-10-25|

FR2390437B1|1982-08-06|

ZA782632B|1979-04-25|

NL7804969A|1978-11-14|

DK203378A|1978-11-11|

HU179924B|1983-01-28|

PL108586B1|1980-04-30|

IT1094585B|1985-08-02|

ATA338778A|1981-01-15|

CA1100975A|1981-05-12|

FR2390437A1|1978-12-08|

IL54664D0|1978-07-31|

AR220707A1|1980-11-28|

PT68006A|1978-06-01|

PT68006B|1979-10-22|

PH14131A|1981-02-26|

BE866833A|1978-11-09|

EG13280A|1982-06-30|

AU3591978A|1979-11-15|

CH633538A5|1982-12-15|

引用文献:

公开号 | 申请日 | 公开日 | 申请人 | 专利标题

DE2324010C3|1973-05-12|1981-10-08|Bayer Ag, 5090 Leverkusen|1-Substituted 2-triazolyl-2-phenoxyethanol compounds, process for their preparation and their use for combating fungi|

DE2324424A1|1973-05-15|1974-12-05|Bayer Ag|ANTIMICROBIAL AGENTS|

DE2325156A1|1973-05-18|1974-12-05|Bayer Ag|FUNGICIDES AND MICROBICIDALS|

DE2333354C2|1973-06-30|1983-12-15|Bayer Ag, 5090 Leverkusen|2-Aryloxy-2- -ethanols and their salts, processes for their preparation and their use as fungicides|

DE2431407C2|1974-06-29|1982-12-02|Bayer Ag, 5090 Leverkusen|1,2,4-Triazol-1-yl-alkanones and alkanols, processes for their preparation and their use as fungicides|

DE2455955A1|1974-11-27|1976-08-12|Bayer Ag|FUNGICIDALS|

DE2455953A1|1974-11-27|1976-08-12|Bayer Ag|FUNGICIDALS|

US4036973A|1975-07-28|1977-07-19|Syntex Inc.|Imidazol-1-yl propane derivatives|

NZ181916A|1975-09-10|1979-01-11|Ici Ltd|1-substituted-1,2,4-triazoles and fungicidal compositions|

DE2547953A1|1975-10-27|1977-04-28|Bayer Ag| -AETHER- DERIVATIVES, PROCESS FOR THEIR MANUFACTURING AND THEIR USE AS FUNGICIDES|DE2758784A1|1977-12-29|1979-07-12|Basf Ag|TRIAZOLYL GLYCOLAETHER|

DE2827968A1|1978-06-26|1980-01-10|Bayer Ag|SULFENYLATED CARBAMOYL TRIAZOLYL-O, N-ACETALS, PROCESS FOR THEIR PRODUCTION AND THEIR USE AS FUNGICIDES|

DE2918801A1|1979-05-10|1980-11-20|Basf Ag|CARBINOLETHER|

DE2923439A1|1979-06-09|1980-12-18|Basf Ag|GLYKOLALDEHYD-N, O-ACETALE, THEIR PRODUCTION AND USE AS FUNGICIDES|

DE2925687A1|1979-06-26|1981-01-22|Basf Ag|TRIAZOLYL GLYCOLETHER CONTAINERS FOR REGULATING PLANT GROWTH|

DE2926280A1|1979-06-29|1981-01-08|Basf Ag|FUNGICIDAL ALPHA -TRIAZOLYL GLYCOLE DERIVATIVES, THEIR PRODUCTION AND USE|

DE2931755A1|1979-08-04|1981-02-19|Bayer Ag|1,2,4-TRIAZOLYL ENOLETHER, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS FUNGICIDES|

DE2931665A1|1979-08-04|1981-02-19|Bayer Ag|IMIDAZOLYL ENOLETHER, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS FUNGICIDES|

DE2931756A1|1979-08-04|1981-02-19|Bayer Ag|ANTIMICROBIAL AGENTS|

DE3019049A1|1980-05-19|1981-12-03|Basf Ag, 6700 Ludwigshafen|NEW AZOLES|

DE3021551A1|1980-06-07|1981-12-24|Bayer Ag, 5090 Leverkusen|4-SUBSTITUTED 1-AZOLYL-1-PHENOXY-3,3-DIMETHYL-BUTAN-2-ONE AND -OLE, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS FUNGICIDES|

DK162882A|1981-04-13|1982-10-14|Searle & Co|IMIDAZOLE DERIVATIVES OR ACID ADDITION SALTS THEREOF, THEIR PREPARATION AND USE|

DE3150204A1|1981-12-18|1983-06-30|Basf Ag, 6700 Ludwigshafen|FUNGICIDAL ALPHA AZOLYL GLYCOLES|

DE3234624C2|1982-09-18|1992-04-30|Bayer Ag, 5090 Leverkusen, De|

US4579862A|1983-07-05|1986-04-01|G. D. Searle & Co.|Certain 1H-imidazol-1-yl-1-lower-alkanoic acid derivatives having anti-thrombotic activity|

法律状态:

优先权:

申请号 | 申请日 | 专利标题

DE19772720949|DE2720949A1|1977-05-10|1977-05-10|AZOLYL ETHER DERIVATIVES, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS FUNGICIDES|

[返回顶部]